Hot pressing of nanocrystalline TiO2 (anatase) ceramics with controlled microstructure

Hot pressing of nanocrystalline TiO2 (anatase) ceramics with controlled microstructure

Hot compaction of nanocrystalline TiO2 (anatase) ceramics. Mechanisms of densification: Grain size and doping effects

The hot compaction of nanocrystalline TiO2 anatase powders is investigated using dilatometry. The constant rate of heating (CRH) method is applied to determine effective activation energies of the processes involved during sintering. Grain size and doping effects are studied, using dopant cations of different radius and charge: Zn, Al, Si, Nb. The results are interpreted by a mechanism includin...

Comparison of Creep Behavior in Alumina Based Ceramics Densified by Spark Plasma Sintering and Hot Pressing

Spark plasma sintering (SPS) method, as plasma activated sintering, is a method applicable for rapid sintering of metals and ceramics. Owing to the advantage of rapid heating, the alumina ceramics obtained by SPS have a grain size and density comparable to those of hot pressed ones. The increase of densification rate may be related to some difference in ion transport characteristics. This study...

The vacuum hot pressing behavior of silicon carbide fibers coated with nanocrystalline Ti–6Al–4V

The vacuum hot pressing (VHP) of silicon carbide monofilaments coated with nanocrystalline Ti–6Al–4V has been studied. During consolidation, very high densification rates were observed, even at temperatures and pressures well below those normally used for processing conventional Ti–6Al–4V. From the cross-sections of partially consolidated specimens, the evolution of coated fiber–fiber contacts ...

Thermal and photochemical reactions of methanol on nanocrystalline anatase TiO2 thin films.

The catalytic and photo-catalytic activity of well-defined anatase TiO2 nanocrystals for the partial oxidation of methanol was investigated using temperature-programmed desorption (TPD) in ultra-high vacuum in order to determine how crystallite size and shape affect reactivity. The TiO2 films used in this study were prepared from well-defined TiO2 nanocrystals synthesized by colloidal methods. ...